| ID | 114284 |
| Author |
Arakawa, Yukihiro
Tokushima University
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Sato, Fumiaki
Tokushima University
Ariki, Kenta
Tokushima University
Minagawa, Keiji
Tokushima University
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Imada, Yasushi
Tokushima University
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|
| Keywords | Flavin
Polymer-supported catalyst
Hydrogenation
Photooxidation
|
| Content Type |
Journal Article
|
| Description | Riboflavin tetramethacrylate (RFlTMA) was prepared as a flavin monomer and copolymerized with ethylene glycol dimethacrylate (EGDMA) under polymerization-induced phase separation conditions. The resulting flavin-containing mesoporous network polymer, poly(RFlTMA-co-EGDMA), was found to be a more effective catalyst than riboflavin tetraacetate (RFlTA), a soluble analogue, for aerobic hydrogenation of olefins despite its heterogeneity, which allowed for its multiple recovery and reuse through simple filtrations and washings without loss in catalytic activity. In addition, the polymeric flavin was demonstrated to be utilized also as an effective photocatalyst in the oxidation of benzyl alcohols.
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| Journal Title |
Tetrahedron Letters
|
| ISSN | 00404039
|
| NCID | AA00861801
AA11539822
|
| Publisher | Elsevier
|
| Volume | 61
|
| Issue | 14
|
| Start Page | 151710
|
| Published Date | 2020-02-04
|
| Rights | © 2020. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
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| EDB ID | |
| DOI (Published Version) | |
| URL ( Publisher's Version ) | |
| FullText File | |
| language |
eng
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| TextVersion |
Author
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| departments |
Science and Technology
Liberal Arts and Sciences
|
