ID | 115353 |
著者 |
Kamikubo, Takahiro
Tokushima University
Okumura, Yuya
Tokushima University
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キーワード | N-Isopropylacrylamide
Heterotactic polymer
Radical polymerization
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資料タイプ |
学術雑誌論文
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抄録 | Radical polymerization of N-isopropylacrylamide in toluene at –40°C in the presence of fourfold amounts of fluorinated alcohols was investigated. The 13C NMR analysis of the obtained polymers suggested that the addition of fluorinated alcohols induced heterotactic-specificity in radical polymerization of NIPAAm, although syndiotactic poly(NIPAAm)s were obtained by adding alkyl alcohols as we have previously reported. To the best of our knowledge, this is the first synthesis of heterotactic poly(NIPAAm).
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掲載誌名 |
Polymer
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ISSN | 00323861
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cat書誌ID | AA11537383
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出版者 | Elsevier
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巻 | 48
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号 | 17
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開始ページ | 4921
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終了ページ | 4925
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発行日 | 2007-07-04
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権利情報 | © 2007. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
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EDB ID | |
出版社版DOI | |
出版社版URL | |
フルテキストファイル | |
言語 |
eng
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著者版フラグ |
著者版
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部局 |
理工学系
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