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ID 115969
タイトル別表記
HYDROGEN-BONDING INTERACTION IN DBI POLYMERIZATION
著者
Higashi, Kousuke Tokushima University
妹尾, 真紀子 Tokushima University
キーワード
di-n-butyl itaconate
13C-NMR
chain-transfer reaction
radical polymerization
hydrogen bond
tacticity
資料タイプ
学術雑誌論文
抄録
We have reported that intramolecular chain-transfer reaction takes place in radical polymerization of itaconates at high temperatures and/or at low monomer concentrations. In this paper, radical polymerizations of di-n-butyl itaconate (DBI) were carried out in toluene at 60°C in the presence of amide compounds. The 13C NMR spectra of the obtained poly(DBI)s indicated that the intramolecular chain-transfer reaction was suppressed as compared with in the absence of amide compounds. The NMR analysis of DBI and N-ethylacetamide demonstrated both 1:1 complex and 1:2 complex were formed at 60°C through a hydrogen-bonding interaction. The ESR analysis of radical polymerization of diisopropyl itconate (DiPI) was conducted in addition to the NMR analysis of the obtained poly(DiPI). It was suggested that the suppression of the intramolecular chain-transfer reaction with the hydrogen-bonding interaction was achieved by controlling the conformation of the side chain at the penultimate monomeric unit of the propagating radical with an isotactic stereosequence.
掲載誌名
Journal of Polymer Science Part A : Polymer Chemistry
ISSN
0887624X
10990518
cat書誌ID
AA1068915X
AA11624127
出版者
Wiley
42
19
開始ページ
4895
終了ページ
4905
発行日
2004-08-25
権利情報
This is the peer reviewed version of the following article: Hirano, T., Higashi, K., Seno, M. and Sato, T. (2004), Reaction control in radical polymerization of di‐n‐butyl itaconate utilizing a hydrogen‐bonding interaction. J. Polym. Sci. A Polym. Chem., 42: 4895-4905., which has been published in final form at https://doi.org/10.1002/pola.20293. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
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出版社版DOI
出版社版URL
フルテキストファイル
言語
eng
著者版フラグ
著者版
部局
理工学系