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ID 114027
Author
Sawano, Eri Tokushima University|Hokkaido University
Content Type
Journal Article
Description
The three-component coupling reaction of 1,1-dibromoalkenes 1, vinylzinc chloride 2, and carbon soft nucleophiles 3 was realized in the presence of the catalytic palladium/Xantphos species, and 1,3-disubstituted allenic products 5 were obtained in yields of up to 77%. The successive two palladium-catalyzed processes, namely the cross-coupling reaction and the allylic substitution, assembled 5 from the easily accessible starting compounds.
Journal Title
ACS Omega
ISSN
24701343
Publisher
ACS Publications
Volume
4
Issue
21
Start Page
19499
End Page
19504
Published Date
2019-11-08
Rights
This is an open access article published under an ACS AuthorChoice License(https://pubs.acs.org/page/policy/authorchoice_termsofuse.html), which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
EDB ID
DOI (Published Version)
URL ( Publisher's Version )
FullText File
language
eng
TextVersion
Publisher
departments
Science and Technology