| ID | 110587 |
| Author |
Arakawa, Yukihiro
Department of Applied Chemistry, Tokushima University
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Oonishi, Takahiro
Department of Applied Chemistry, Tokushima University
Kohda, Takahiro
Department of Applied Chemistry, Tokushima University
Minagawa, Keiji
Department of Applied Chemistry, Tokushima University|Institute of Liberal Arts and Sciences, Tokushima University
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Imada, Yasushi
Department of Applied Chemistry, Tokushima University
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|
| Keywords | environmentally benign
flavinium salt
ion-exchange resin
organocatalysis
oxidation
|
| Content Type |
Journal Article
|
| Description | We developed a safe, simple, inexpensive, and environmentally benign method for preparing N(5)-ethylated flavinium organocatalysts without using any hazardous reagents or inert conditions as previously required. 5-Ethyl-3-methyllumiflavinium cation was prepared from its reduced form by NaNO2-free aerobic oxidation, which was subsequently extracted onto commercial cation-exchange resins under NaClO4-free conditions. The resulting resin-immobilized flavinium salts were found to be effective organocatalysts for aerobic oxidation reactions.
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| Journal Title |
ChemSusChem
|
| ISSN | 18645631
1864564X
|
| NCID | AA12309282
|
| Publisher | Wiley
|
| Volume | 9
|
| Issue | 19
|
| Start Page | 2769
|
| End Page | 2773
|
| Sort Key | 2769
|
| Published Date | 2016-08-24
|
| Remark | © 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
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| EDB ID | |
| URL ( Publisher's Version ) | |
| FullText File | |
| language |
eng
|
| TextVersion |
Author
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| departments |
Science and Technology
Liberal Arts and Sciences
|
