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ID 110587
Author
Oonishi, Takahiro Department of Applied Chemistry, Tokushima University
Kohda, Takahiro Department of Applied Chemistry, Tokushima University
Minagawa, Keiji Department of Applied Chemistry, Tokushima University|Institute of Liberal Arts and Sciences, Tokushima University Tokushima University Educator and Researcher Directory KAKEN Search Researchers
Keywords
environmentally benign
flavinium salt
ion-exchange resin
organocatalysis
oxidation
Content Type
Journal Article
Description
We developed a safe, simple, inexpensive, and environmentally benign method for preparing N(5)-ethylated flavinium organocatalysts without using any hazardous reagents or inert conditions as previously required. 5-Ethyl-3-methyllumiflavinium cation was prepared from its reduced form by NaNO2-free aerobic oxidation, which was subsequently extracted onto commercial cation-exchange resins under NaClO4-free conditions. The resulting resin-immobilized flavinium salts were found to be effective organocatalysts for aerobic oxidation reactions.
Journal Title
ChemSusChem
ISSN
18645631
1864564X
NCID
AA12309282
Publisher
Wiley
Volume
9
Issue
19
Start Page
2769
End Page
2773
Sort Key
2769
Published Date
2016-08-24
Remark
© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
EDB ID
URL ( Publisher's Version )
FullText File
language
eng
TextVersion
Author
departments
Science and Technology
Liberal Arts and Sciences