ID 113099
Author
Hirota, Kenji Tokushima University
Takagi, Katsuhiro Tokushima University
Hanasaku, Kenichi Tokushima University
Hasezaki, Kana L. Kyushu University
Saito, Hikaru Kyushu University
Hata, Satoshi Kyushu University
Keywords
Functional alloys
Thermoelectric properties
Mechanical alloying and milling
Grain boundary
Electron energy-loss spectroscopy (EELS)
Thermoelectric power generation
Content Type
Journal Article
Description
The effects of additional graphite in (Bi0.3Sb1.7Te3.1)1−xCx (x = 0, 0.004, 0.012, 0.032, 0.06, and 0.12) prepared by mechanical alloying followed by hot pressing were investigated. Carbon was added to obtain a low thermal conductivity via phonon scattering. The samples were examined by X-ray diffraction, scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy, and electron energy-loss spectroscopy (EELS). EELS can be used to investigate the distributions of light elements such as carbon. The diffraction peaks indicated a single-phase Bi2Te3–Sb2Te3 solid solution. All the specimens were p-type semiconductors and SEM and TEM images showed dense without coarse grains. Agglomeration along the grain boundaries and inhomogeneous dispersion of carbon was observed by EELS. (Bi0.3Sb1.7Te3.1)0.88C0.12 grains wrapped by carbon layers of thickness approximately 50 nm were observed. The thermal conductivity of (Bi0.3Sb1.7Te3.1)1−xCx increased with increasing x. It is considered that the presence of a large amount of carbon affected the thermal conductivity of the Bi0.3Sb1.7Te3.1 matrix because the thermal conductivity of carbon is much higher than that of Bi0.3Sb1.7Te3.1 and the carbon was dispersed inhomogeneously. Bi0.3Sb1.7Te3.1 without additional graphite had a maximum dimensionless figure of merit ZT = 1.1. The ZT value decreased, and varied from 0.8 to 1.0, for (Bi0.3Sb1.7Te3.1)1−xCx. The results show that inhomogeneously dispersed carbon did not improve the thermoelectric properties of Bi0.3Sb1.7Te3.1.
Journal Title
Intermetallics
ISSN
09669795
NCID
AA10947696
AA11530351
Publisher
Elsevier
Volume
109
Start Page
1
End Page
7
Published Date
2019-03-09
Remark
本文は2021-03-09以降公開予定
Rights
© 2019. This manuscript version is made available under the CC-BY-NC-ND 4.0 license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
DOI (Published Version)
URL ( Publisher's Version )
language
eng
TextVersion
その他
departments
Science and Technology