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ID 113450
Author
Kang, Bubwoong Kyoto University
Wang, Yinli Kyoto University
Kuwano, Satoru Kyoto University
Yamaoka, Yousuke Kyoto University
Takasu, Kiyosei Kyoto University
Content Type
Journal Article
Description
A highly site-selective N-heterocyclic carbene (NHC)-catalyzed benzoin-type cyclization of unsymmetrical dialdoses is developed to enable a divergent cyclitol synthesis. The choice of chiral NHCs and protecting groups affects the site-selectivity. The resulting inososes are converted into epi-, muco- and myo-inositol, and their chiral protected derivatives are formed in good yields.
Journal Title
Chemical Communications
ISSN
13597345
1364548X
NCID
AA11071130
AA12455105
Publisher
The Royal Society of Chemistry
Volume
53
Issue
32
Start Page
4469
End Page
4472
Published Date
2017-03-29
Rights
©The Royal Society of Chemistry 2017
EDB ID
DOI (Published Version)
URL ( Publisher's Version )
FullText File
language
eng
TextVersion
Author
departments
Pharmaceutical Sciences