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ID 115167
Title Alternative
Oxa- and Azacycle-formation via Migrative Cyclization of Sulfonylalkynol and Sulfonylalkynamide with NHeterocyclic Carbene
Author
Wang, Yinli Kyoto University
Oriez, Raphaël Kyoto University
Kuwano, Satoru Kyoto University
Yamaoka, Yousuke Kyoto University
Takasu, Kiyosei Kyoto University
Content Type
Journal Article
Description
An N-heterocyclic carbene promotes cyclization of sulfonylalkynols and sulfonylalkynamides that accompanies 1,2-migration of the sulfonyl groups. This reaction provides a novel access to oxa- and azacycles possessing a pendent vinyl sulfone functionality, which in turn is amenable for further transformations.
Journal Title
The Journal of Organic Chemistry
ISSN
00223263
15206904
NCID
AA00704100
AA12097242
Publisher
ACS Publications
Volume
81
Issue
6
Start Page
2652
End Page
2664
Published Date
2016-03-01
Rights
This document is the Accepted Manuscript version of a Published Work that appeared in final form in The Journal of Organic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.joc.6b00182.
EDB ID
DOI (Published Version)
URL ( Publisher's Version )
FullText File
language
eng
TextVersion
Author
departments
Pharmaceutical Sciences