| ID | 116129 |
| Author |
Yoshida, Ken
Tokushima University
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Yoshioka, Haruka
Tokushima University
Ushigusa, Natsuko
Tokushima University
Nakahara, Masaru
Kyoto University
|
| Keywords | Film forming amines
Supercritical water
Nuclear magnetic resonance
|
| Content Type |
Journal Article
|
| Description | A 14N and 1H NMR spectroscopic study 1 was carried out to shed light on the microscopic aspects of the reaction of model alkylamines at a supercritical temperature of 400 °C. It is disclosed that NH3 and ROH (R = CH3CH2 and CH3 (CH2)3) are initially produced from the hydrolysis of ethylamine and butylamine, respectively. When the water density is doubled from 0.2 g cm−3, the pseudo-first-order reaction rate is markedly enhanced beyond the linear response. It suggests that the transition state of C-N bond cleavage is in a dipolar (ionic) state that can be more stabilized due to the many-body solvation by highly polar water molecules at a higher density.
|
| Journal Title |
Chemistry Letters
|
| ISSN | 13480715
|
| NCID | AA12179675
|
| Publisher | The Chemical Society of Japan
|
| Volume | 50
|
| Issue | 2
|
| Start Page | 316
|
| End Page | 319
|
| Published Date | 2020-11-20
|
| Rights | © 2021 The Chemical Society of Japan
|
| EDB ID | |
| DOI (Published Version) | |
| URL ( Publisher's Version ) | |
| FullText File | |
| language |
eng
|
| TextVersion |
Author
|
| departments |
Science and Technology
|
