ID 71071
Title Alternative
UV-LED を光源とする光開始立体特異性リビングラジカル重合の開発
Author
Hirano, Tomohiro Department of Chemical Science and Technology, The University of Tokushima Tokushima University Educator and Researcher Directory KAKEN Search Researchers
Nasu, Shou Department of Chemical Science and Technology, The University of Tokushima
Kamiike, Ryota Department of Chemical Science and Technology, The University of Tokushima
Ute, Koichi Department of Chemical Science and Technology, The University of Tokushima Tokushima University Educator and Researcher Directory KAKEN Search Researchers
Keywords
N-isopropylacrylamide
Radical Polymerization
Stereoregularity
Living Polymerization
Content Type
Departmental Bulletin Paper
Description
Effect of simple alkyl alcohol on radical polymerization of N-isopropylacrylamide (NIPAAm)
in toluene at low temperatures was investigated. We succeeded in inducing syndiotactic-specificity
and accelerating polymerization reaction at the same time by adding simple alkyl alcohols into
NIPAAm polymerization. Furthermore, effect of chain transfer agent on NIPAAm polymerization at
low temperatures was also examined. Living nature was observed with use of LED as UV light
source even for the low-temperature radical polymerization.
Journal Title
徳島大学大学院ソシオテクノサイエンス研究部研究報告
ISSN
21859094
NCID
AA12214889
Volume
55
Start Page
44
End Page
50
Sort Key
44
Published Date
2010-04
EDB ID
FullText File
language
eng
departments
Science and Technology