ID | 74512 |
Title Transcription | サンカ テツケイ ネンショウ ショクバイ ノ ディーゼル ハイキ ガス ショリ ギジュツ エノ オウヨウ
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Title Alternative | Application of Iron Oxide Combustion Catalysts to After-Treatment System of Diesel Engine
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Author |
Murai, Kei-ichiro
Department of Advanced Materials, Institute of Technology and Science, The University of Tokushima
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Tojo, Suguru
Course in Chemical Science and Technology, Graduate School of Engineering, The University of Tokushima
Yamaguchi, Takafumi
College of Earth and Life Environmental Engineering, Graduate School of Advanced Technology and Science, The University of Tokushima
Moriga, Toshihiro
Department of Advanced Materials, Institute of Technology and Science, The University of Tokushima
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Kidoguchi, Yoshiyuki
Department of Energy System, Institute of Technology and Science, The University of Tokushima
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Keywords | Iron oxide
Combustion Catalyst
Oxidation
Alumina Support
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Content Type |
Departmental Bulletin Paper
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Description | Iron oxides which were supported on three kinds of alumina (γ-Al2O3, χ-Al2O3 and
activated-Al2O3) were prepared for oxidation catalysts on an after-treatment system of diesel engine. In methane oxidation experiment, we found that the hematite (α-Fe2O3), which was synthesized from goethite (α-FeOOH), supported on χ-Al2O3 has the highest catalytic activity (over 70% in CH4 conversion) at 227K than the other catalysts. Also in the redox reaction between NOx and activated-carbon as substitute for soot, the catalyst supported on χ-Al2O3 showed the highest performance and CO gas was not observed in the products. It is concluded that in α-Fe2O3/χ-Al2O3 catalyst, α-Fe2O3 exists mainly on the surface of the support, because of flatness of the surface of χ-Al2O3. On the other hand, in the case of α-Fe2O3/γ-Al2O3 catalyst, as the surface of support, γ-Al2O3, is uneven, α-Fe2O3 do not partially exist on the surface but in the pores. |
Journal Title |
徳島大学大学院ソシオテクノサイエンス研究部研究報告
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ISSN | 21859094
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NCID | AA12214889
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Volume | 53
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Start Page | 28
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End Page | 32
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Sort Key | 28
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Published Date | 2008
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FullText File | |
language |
jpn
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departments |
Science and Technology
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