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ID 113937
Author
Hiroyama, Yuta Tokushima University
Fukayama, Shintaro Tokushima University
Keywords
Piperazine-2,5-dione
N-methylation
Folded conformation
Extended conformation
CH/π interaction
X-ray crystal structure
Content Type
Journal Article
Description
N4-Methylation of (3S,6S)-3-alkyl-6-benzylpiperazine-2,5-diones (S,S)-1a–c was found to change their folded conformation to an extended conformation. Conformational aspects of N1- and/or N4-methylated (S,S)-1a–c were revealed by single crystal X-ray crystallography and 1H NMR spectroscopy.
Journal Title
Journal of Molecular Structure
ISSN
00222860
NCID
AA00702852
AA11533407
Publisher
Elsevier
Volume
1116
Start Page
37
End Page
44
Published Date
2016-03-09
Rights
© 2016. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
EDB ID
DOI (Published Version)
URL ( Publisher's Version )
FullText File
language
eng
TextVersion
Author
departments
Pharmaceutical Sciences