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ID 114094
Title Alternative
Synthesis of Allenyl Esters by Horner-Wadsworth-Emmons Reactions of Ketenes Mediated by i-PrMgBr
Author
Matsumoto, Tomoya Tokushima University
Yano, Teppei Tokushima University
Toguchi, Munehisa Tokushima University
Keywords
Horner-Wadsworth-Emmons reaction
allene
ketene
Grignard reagent
fluorine
Content Type
Journal Article
Description
The synthesis of conjugated allenyl esters (trisubstituted allenes) was achieved by the Mg(II)-mediated Horner-Wadsworth-Emmons reaction of methyl bis(2,2,2-trifluoroethyl)phosphonoacetate with di-substituted ketenes. In addition, a novel access to α-fluorinated allenyl carboxamides (tetra-substituted allenes) is presented.
Journal Title
Synlett
ISSN
09365214
14372096
NCID
AA10731110
Publisher
Georg Thieme Verlag
Volume
26
Issue
15
Start Page
2135
End Page
2138
Published Date
2015-08-10
EDB ID
DOI (Published Version)
URL ( Publisher's Version )
FullText File
language
eng
TextVersion
Author
departments
Pharmaceutical Sciences