Tagami, Takuma Tokushima University
Arakawa, Yukihiro Tokushima University Tokushima University Educator and Researcher Directory KAKEN Search Researchers
Minagawa, Keiji Tokushima University Tokushima University Educator and Researcher Directory KAKEN Search Researchers
Imada, Yasushi Tokushima University Tokushima University Educator and Researcher Directory KAKEN Search Researchers
An isoalloxazine (flavin) ring system and a secondary amine have been integrated through a short peptide linker with the aim of using photons as efficient as possible in photoredox/enamine dual catalysis. We herein report a peptide-bridged flavin-amine hybrid that can catalyze α-oxyamination of aldehydes with TEMPO under weak blue light irradiation to achieve an extremely high quantum yield of reaction (Φ = 0.80).
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.9b02567.
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