Aerobic oxidation of alcohols using bismuth bromide as a catalyst

Ueno, Masaharu; Ohmura, Satoshi D.; Wada, Makoto; Miyoshi, Norikazu

doi:10.1016/j.tetlet.2019.01.034

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Use this link to cite this item : https://repo.lib.tokushima-u.ac.jp/112992

ID	112992
Author	Ueno, Masaharu Tokushima University Tokushima University Educator and Researcher Directory KAKEN Search Researchers Ohmura, Satoshi D. Tokushima University KAKEN Search Researchers Wada, Makoto Tokushima University Tokushima University Educator and Researcher Directory KAKEN Search Researchers Miyoshi, Norikazu Tokushima University Tokushima University Educator and Researcher Directory KAKEN Search Researchers
Keywords	Bismuth salts Aerobic oxidation Alcohols Green Sustainable Chemistry
Content Type	Journal Article
Description	We developed an environmentally friendly method for aerobic oxidation of alcohols using a commercially available, relatively benign bismuth salt as a catalyst. We found that the catalytic combination of BiBr3 with nitric acid is key for enhancing the reactivity. The reaction proceeds well under air, making the use of pure oxygen unnecessary. Each of the primary or secondary alcohols tested was oxidized to the corresponding aldehydes or ketones using this protocol.
Journal Title	Tetrahedron Letters
ISSN	00404039
NCID	AA00861801 AA11539822
Publisher	Elsevier
Volume	60
Issue	7
Start Page	570
End Page	573
Published Date	2019-01-18
Remark	This is the preprint version of a paper already published in Tetrahedron Letters, Volume 60, Issue 7, 2019, Pages 570-573.
EDB ID	349611
DOI (Published Version)	10.1016/j.tetlet.2019.01.034
URL ( Publisher's Version )	https://doi.org/10.1016/j.tetlet.2019.01.034
FullText File	tetlet_60_7_570_preprint.pdf 264 KB tetlet_60_7_570_accepted.pdf 245 KB
language	eng
TextVersion	Author
departments	Science and Technology