| ID | 113017 |
| Author |
Ogasawara, Masamichi
Tokushima University|Hokkaido University
Tokushima University Educator and Researcher Directory
Sasa, Hirotaka
Ritsumeikan University
Hu, Hao
Tokushima University|Hokkaido University
Amano, Yuta
Ritsumeikan University
Nakajima, Hikaru
Hokkaido University
Takenaga, Naoko
Meijo University
Nakajima, Kiyohiko
Aichi Universiy of Education
Kita, Yasuyuki
Ritsumeikan University
Takahashi, Tamotsu
Hokkaido University
Dohi, Toshifumi
Ritsumeikan University
|
| Content Type |
Journal Article
|
| Description | The C2-symmetric tetralin-fused 1,4-diiodo-1,3-butadiene derivatives, (Z,Z)-2,3-di(1-iodoalkylidene)tetralin 1a-c, are atropisomeric and can be resolved into the two persistent axially chiral enantiomers by HPLC on a chiral stationary phase. The enantiomerically pure compounds can serve as chiral organocatalysts for dearomatizing spirolactonization to show good performances in up to 73 % ee.
|
| Journal Title |
Organic Letters
|
| ISSN | 15237060
15237052
|
| NCID | AA11347843
AA1218968X
|
| Publisher | ACS Publications
|
| Volume | 19
|
| Issue | 15
|
| Start Page | 4102
|
| End Page | 4105
|
| Published Date | 2017-07-20
|
| Rights | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.7b01876.
|
| EDB ID | |
| DOI (Published Version) | |
| URL ( Publisher's Version ) | |
| FullText File | |
| language |
eng
|
| TextVersion |
Author
|
| departments |
Science and Technology
|
