Noncovalent Modification Strategy with Achiral Phosphoric Acid Diesters for Designing a Chiral Brønsted Base Organocatalyst

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Use this link to cite this item : https://repo.lib.tokushima-u.ac.jp/117573

ID	117573
Author	Hara, Momoko Tokushima University Ogawa, Aya Tokushima University Minagawa, Keiji Tokushima University Tokushima University Educator and Researcher Directory KAKEN Search Researchers Imada, Yasushi Tokushima University Tokushima University Educator and Researcher Directory KAKEN Search Researchers Arakawa, Yukihiro Tokushima University Tokushima University Educator and Researcher Directory KAKEN Search Researchers
Keywords	Organocatalyst Achiral phosphoric acid diester Noncovalent modification
Content Type	Journal Article
Description	A strategy for designing chiral Brønsted base organocatalysts through noncovalent modification of a chiral dibasic molecule with an achiral phosphoric acid diester is introduced for the first time. Such a molecular modification concept utilizing acid-base interactions may facilitate the on-demand design of asymmetric organocatalysts, as preliminarily demonstrated in this work.
Journal Title	Bulletin of the Chemical Society of Japan
ISSN	13480634
Publisher	The Chemical Society of Japan
Volume	95
Issue	4
Start Page	553
End Page	555
Published Date	2022-02-23
Rights	© 2022 The Chemical Society of Japan
EDB ID	384321
DOI (Published Version)	10.1246/bcsj.20210462
URL ( Publisher's Version )	https://doi.org/10.1246/bcsj.20210462
FullText File	bcsj_95_4_553.pdf 795 KB
language	eng
TextVersion	Author
departments	Liberal Arts and Sciences