| ID | 115353 |
| Author |
Hirano, Tomohiro
Tokushima University
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Kamikubo, Takahiro
Tokushima University
Okumura, Yuya
Tokushima University
|
| Keywords | N-Isopropylacrylamide
Heterotactic polymer
Radical polymerization
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| Content Type |
Journal Article
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| Description | Radical polymerization of N-isopropylacrylamide in toluene at –40°C in the presence of fourfold amounts of fluorinated alcohols was investigated. The 13C NMR analysis of the obtained polymers suggested that the addition of fluorinated alcohols induced heterotactic-specificity in radical polymerization of NIPAAm, although syndiotactic poly(NIPAAm)s were obtained by adding alkyl alcohols as we have previously reported. To the best of our knowledge, this is the first synthesis of heterotactic poly(NIPAAm).
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| Journal Title |
Polymer
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| ISSN | 00323861
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| NCID | AA11537383
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| Publisher | Elsevier
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| Volume | 48
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| Issue | 17
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| Start Page | 4921
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| End Page | 4925
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| Published Date | 2007-07-04
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| Rights | © 2007. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
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| EDB ID | |
| DOI (Published Version) | |
| URL ( Publisher's Version ) | |
| FullText File | |
| language |
eng
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| TextVersion |
Author
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| departments |
Science and Technology
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