| ID | 111039 |
| Title Alternative | 脱原油資源を目指した接触酸化脱水素反応による汎用工業原料の合成研究
|
| Author |
Sugiyama, Shigeru
Tokushima University
Tokushima University Educator and Researcher Directory
KAKEN Search Researchers
Nagai, Yuya
Tokushima University
Sakamoto, Naotaka
Tokushima University
Ohtake, Naotaka
Tokushima University
|
| Keywords | 1-Butene
1,3-Butadiene
α-Bi2Mo3O12
Cerium doping
Oxidative dehydrogenation
|
| Content Type |
Departmental Bulletin Paper
|
| Description | To prepare 1,3-butadiene, one of versatile chemicals, from 1-butene, one of the main components in liquefied petroleum gas (LPG), the oxidative dehydrogenation of 1-butene on α-Bi2Mo3O12 doped with cerium was examined. Regardless to the doped amount of cerium, the conversion of 1-butene was constant while the selectivity to 1,3-butadiene decreased with the doped amount of cerium, while the selectivities to 2-butenes, CO and CO2 increased. It is concluded that the introduction of cerium into α- Bi2Mo3O12 resulted in the enhancement of the greater acidic nature of the catalyst while the mild acidic nature of the catalyst seems to be suitable for the effective synthesis of 1,3-butadiene from 1-butene via the oxidative dehydrogenation.
|
| Journal Title |
Bulletin of Institute of Technology and Science
|
| ISSN | 21859094
|
| NCID | AA12214889
|
| Volume | 61
|
| Start Page | 1
|
| End Page | 5
|
| Sort Key | 1
|
| Published Date | 2016
|
| Rights | この論文の著作権は徳島大学ソシオテクノサイエンス研究部にあります。
|
| EDB ID | |
| FullText File | |
| language |
eng
|
| TextVersion |
Publisher
|
| departments |
Science and Technology
|
