ID | 119094 |
Author |
Kawatani, Ryo
Nara Institute of Science and Technology
Nishiyama, Yasuhiro
Nara Institute of Science and Technology
Kamikubo, Hironari
Nara Institute of Science and Technology
Kakiuchi, Kiyomi
Nara Institute of Science and Technology
Ajiro, Hiroharu
Nara Institute of Science and Technology|JST PRESTO
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Keywords | Thermosensitive
Nanoparticle
N-Vinylamide
Azobenzene
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Content Type |
Journal Article
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Description | Thermal and photo responsive copolymer based on N-vinylamide backbone was designed. Methoxyethyl group and azobenzene were selected to improve hydrophilicity and photoresponsive moieties, respectively. The N-(methoxyethyl)-N-vinylformamide was synthesized and copolymerized with N-vinylformamide by free radical polymerization. In order to control the nanosized structures, poly(N-vinylformamide) derivatives bearing azobenzene at the N-position near to the vinyl polymer main chain were synthesized by polymer reaction with the poly(N-vinylformamide-co-N-(methoxyethyl)-N-vinylformamide) and azobenzene. Aggregation size of the multi-stimuli-responsive polymer was controlled by preparation of the hydrophobic interaction at around N-position.
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Journal Title |
Nanoscale Research Letters
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ISSN | 1556276X
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Publisher | Springer Nature
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Volume | 12
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Start Page | 461
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Published Date | 2017-07-21
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Rights | This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.
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language |
eng
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