ID 111039
Title Alternative
脱原油資源を目指した接触酸化脱水素反応による汎用工業原料の合成研究
Author
Nagai, Yuya Tokushima University
Sakamoto, Naotaka Tokushima University
Ohtake, Naotaka Tokushima University
Keywords
1-Butene
1,3-Butadiene
α-Bi2Mo3O12
Cerium doping
Oxidative dehydrogenation
Content Type
Departmental Bulletin Paper
Description
To prepare 1,3-butadiene, one of versatile chemicals, from 1-butene, one of the main components in liquefied petroleum gas (LPG), the oxidative dehydrogenation of 1-butene on α-Bi2Mo3O12 doped with cerium was examined. Regardless to the doped amount of cerium, the conversion of 1-butene was constant while the selectivity to 1,3-butadiene decreased with the doped amount of cerium, while the selectivities to 2-butenes, CO and CO2 increased. It is concluded that the introduction of cerium into α- Bi2Mo3O12 resulted in the enhancement of the greater acidic nature of the catalyst while the mild acidic nature of the catalyst seems to be suitable for the effective synthesis of 1,3-butadiene from 1-butene via the oxidative dehydrogenation.
Journal Title
Bulletin of Institute of Technology and Science
ISSN
21859094
NCID
AA12214889
Volume
61
Start Page
1
End Page
5
Sort Key
1
Published Date
2016
Rights
この論文の著作権は徳島大学ソシオテクノサイエンス研究部にあります。
EDB ID
FullText File
language
eng
TextVersion
Publisher
departments
Science and Technology