ID 113017
Author
Sasa, Hirotaka Ritsumeikan University
Hu, Hao Tokushima University|Hokkaido University
Amano, Yuta Ritsumeikan University
Nakajima, Hikaru Hokkaido University
Takenaga, Naoko Meijo University
Nakajima, Kiyohiko Aichi Universiy of Education
Kita, Yasuyuki Ritsumeikan University
Takahashi, Tamotsu Hokkaido University
Dohi, Toshifumi Ritsumeikan University
Content Type
Journal Article
Description
The C2-symmetric tetralin-fused 1,4-diiodo-1,3-butadiene derivatives, (Z,Z)-2,3-di(1-iodoalkylidene)tetralin 1a-c, are atropisomeric and can be resolved into the two persistent axially chiral enantiomers by HPLC on a chiral stationary phase. The enantiomerically pure compounds can serve as chiral organocatalysts for dearomatizing spirolactonization to show good performances in up to 73 % ee.
Journal Title
Organic Letters
ISSN
15237060
15237052
NCID
AA11347843
AA1218968X
Publisher
ACS Publications
Volume
19
Issue
15
Start Page
4102
End Page
4105
Published Date
2017-07-20
Remark
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.7b01876.
EDB ID
DOI (Published Version)
URL ( Publisher's Version )
FullText File
language
eng
TextVersion
Author
departments
Science and Technology