ID 113017
著者
小笠原, 正道 Tokushima University|Hokkaido University 徳島大学 教育研究者総覧
Sasa, Hirotaka Ritsumeikan University
Hu, Hao Tokushima University|Hokkaido University
Amano, Yuta Ritsumeikan University
Nakajima, Hikaru Hokkaido University
Takenaga, Naoko Meijo University
Nakajima, Kiyohiko Aichi Universiy of Education
Kita, Yasuyuki Ritsumeikan University
Takahashi, Tamotsu Hokkaido University
Dohi, Toshifumi Ritsumeikan University
資料タイプ
学術雑誌論文
抄録
The C2-symmetric tetralin-fused 1,4-diiodo-1,3-butadiene derivatives, (Z,Z)-2,3-di(1-iodoalkylidene)tetralin 1a-c, are atropisomeric and can be resolved into the two persistent axially chiral enantiomers by HPLC on a chiral stationary phase. The enantiomerically pure compounds can serve as chiral organocatalysts for dearomatizing spirolactonization to show good performances in up to 73 % ee.
掲載誌名
Organic Letters
ISSN
15237060
15237052
cat書誌ID
AA11347843
AA1218968X
出版者
ACS Publications
19
15
開始ページ
4102
終了ページ
4105
発行日
2017-07-20
備考
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.7b01876.
EDB ID
出版社版DOI
出版社版URL
フルテキストファイル
言語
eng
著者版フラグ
著者版
部局
理工学系