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ID 117574
Author
Takechi, Nao Tokushima University
Yamanomoto, Ken Tokushima University
Keywords
Flavin
Peptide
Aerobic oxidation
DFT calculation
Content Type
Journal Article
Description
The original flavopeptide catalyst, 3-FlC2-L-Pro-L-Tyr-L-Asp-Ado-NH-PS (Fl-PepLLL), and its diastereomers including Fl-PepDDL, Fl-PepLDL, and Fl-PepDLL were synthesized to investigate the correlation between their catalytic activity and stereochemistry. The results and related computations showed the importance of intramolecular hydrogen bonds involving the Asp residue in their 4a-hydroperoxy forms for the catalysis.
Journal Title
Tetrahedron Letters
ISSN
00404039
NCID
AA00861801
AA11539822
Publisher
Elsevier
Volume
73
Start Page
153107
Published Date
2021-04-22
Rights
© 2021. This manuscript version is made available under the CC-BY-NC-ND 4.0 license https://creativecommons.org/licenses/by-nc-nd/4.0/
EDB ID
DOI (Published Version)
URL ( Publisher's Version )
FullText File
language
eng
TextVersion
Author
departments
Science and Technology
Liberal Arts and Sciences