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ID 115148
Author
Moriuchi, Toshiyuki Osaka City University
Moriuchi-Kawakami, Takayo Osaka Institute of Technology
Keywords
chirality induction
helical chirality
bioorganometallic conjugate
dipeptide
nucleobase
ferrocene
organogold(I)
self-assembly
hydrogen bond
Au(I)–Au(I) interaction
Content Type
Journal Article
Description
Considerable attention has been given to the research field of bioorganometallic chemistry, which is a hybrid chemistry field between biology and organometallic chemistry. The introduction of biomolecules, which have hydrogen bonding sites and chiral centers, into organometallic compounds is a promising strategy to construct chirality-organized bioorganometallic conjugates. This feature paper sketches an outline of induction of helical chirality into bioorganometallic conjugates by the control of a torsional twist of the organometallic moiety. Topics covered included control of the helical chirality of 1,n′-disubstituted ferrocene moieties in ferrocene-dipeptide conjugates, and the chirality induction of the Au(I)–Au(I) axis in the dinuclear organogold(I)-uracil conjugates.
Journal Title
Inorganics
ISSN
23046740
Publisher
MDPI
Volume
6
Issue
4
Start Page
111
Published Date
2018-10-13
Rights
© 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
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DOI (Published Version)
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language
eng
TextVersion
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departments
Science and Technology