ID 111892
Author
Jichu, Takahisa Tokushima University
Aihara, Keisuke Tokushima University
Kohiki, Taiki Tokushima University
Nishida, Kodai Tokushima University
Keywords
organocatalyst
amino thiourea
asymmetric catalyst
hydrophobic anchor
recyclable catalyst
Content Type
Journal Article
Description
A novel recyclable thiourea-based, asymmetric organocatalyst containing a hydrophobic anchor has been developed. The chemical nature of the hydrophobic anchor contributes to the desirable characteristics of the recyclable catalyst. The hydrophobic anchor-tagged thiourea catalyst is highly soluble in less polar solvents compatible to the amino thiourea catalyst-mediated asymmetric reactions, but sparingly soluble in polar solvents used for recycle process. This asymmetric catalyst delivers a catalytic performance comparable to that of a parent catalyst and can be readily recycled from reactions.
Journal Title
ChemCatChem
ISSN
18673899
NCID
AA12433532
Publisher
WILEY-VCH Verlag GmbH & Co. KGaA
Volume
10
Issue
16
Start Page
3402
End Page
3405
Published Date
2018-07-11
Remark
This is the peer reviewed version of the following article: T. Jichu, T. Inokuma, K. Aihara, T. Kohiki, K. Nishida, A. Shigenaga, K.-i. Yamada, A. Otaka, ChemCatChem 2018, 10, 3402., which has been published in final form at https://doi.org/10.1002/cctc.201800714. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions
EDB ID
DOI (Published Version)
URL ( Publisher's Version )
FullText File
language
eng
TextVersion
Author
departments
Pharmaceutical Sciences