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ID 119093
Author
Kawatani, Ryo Nara Institute of Science and Technology
Kan, Kai Nara Institute of Science and Technology
Kelland, Malcolm A. University of Stavanger
Akashi, Mitsuru Osaka University
Ajiro, Hiroharu Nara Institute of Science and Technology|JST-PREST
Keywords
Poly(N-vinylamide)
Lower critical solution temperature (LCST)
Thermosensitive
Content Type
Journal Article
Description
N-Vinylamide derivatives, such as N-n-butyl-N-vinylformamides and N-iso-butyl-N-vinylformamides were synthesized and copolymerized with N-vinylformamide and N-methyl-N-vinylacetamide. Lower critical solution temperature values of the copolymers were observed at a wide range of temperatures. Thermosensitive behaviors of copolymers were controlled not only by the induction rate of alkylation of N-vinylamides at the amide position but also by the chemical structures, including hydrogen atom of secondary amide group.
Journal Title
Chemistry Letters
ISSN
13480715
Publisher
Oxford University Press|Chemical Society of Japan
Volume
45
Issue
6
Start Page
589
End Page
591
Published Date
2016-03-03
Rights
This is a pre-copyedited, author-produced version of an article accepted for publication in Chemistry Letters following peer review. The version of record Ryo Kawatani, Kai Kan, Malcolm A Kelland, Mitsuru Akashi, Hiroharu Ajiro, Remarkable Effect on Thermosensitive Behavior Regarding Alkylation at the Amide Position of Poly(N-vinylamide)s, Chemistry Letters, Volume 45, Issue 6, June 2016, Pages 589–591, is available online at: https://doi.org/10.1246/cl.160145
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language
eng
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