ID | 119093 |
Author |
Kawatani, Ryo
Nara Institute of Science and Technology
Kan, Kai
Nara Institute of Science and Technology
Kelland, Malcolm A.
University of Stavanger
Akashi, Mitsuru
Osaka University
Ajiro, Hiroharu
Nara Institute of Science and Technology|JST-PREST
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Keywords | Poly(N-vinylamide)
Lower critical solution temperature (LCST)
Thermosensitive
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Content Type |
Journal Article
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Description | N-Vinylamide derivatives, such as N-n-butyl-N-vinylformamides and N-iso-butyl-N-vinylformamides were synthesized and copolymerized with N-vinylformamide and N-methyl-N-vinylacetamide. Lower critical solution temperature values of the copolymers were observed at a wide range of temperatures. Thermosensitive behaviors of copolymers were controlled not only by the induction rate of alkylation of N-vinylamides at the amide position but also by the chemical structures, including hydrogen atom of secondary amide group.
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Journal Title |
Chemistry Letters
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ISSN | 13480715
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Publisher | Oxford University Press|Chemical Society of Japan
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Volume | 45
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Issue | 6
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Start Page | 589
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End Page | 591
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Published Date | 2016-03-03
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Rights | This is a pre-copyedited, author-produced version of an article accepted for publication in Chemistry Letters following peer review. The version of record Ryo Kawatani, Kai Kan, Malcolm A Kelland, Mitsuru Akashi, Hiroharu Ajiro, Remarkable Effect on Thermosensitive Behavior Regarding Alkylation at the Amide Position of Poly(N-vinylamide)s, Chemistry Letters, Volume 45, Issue 6, June 2016, Pages 589–591, is available online at: https://doi.org/10.1246/cl.160145
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language |
eng
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