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ID 119093
著者
川谷, 諒 Nara Institute of Science and Technology
Kan, Kai Nara Institute of Science and Technology
Kelland, Malcolm A. University of Stavanger
Akashi, Mitsuru Osaka University
Ajiro, Hiroharu Nara Institute of Science and Technology|JST-PREST
キーワード
Poly(N-vinylamide)
Lower critical solution temperature (LCST)
Thermosensitive
資料タイプ
学術雑誌論文
抄録
N-Vinylamide derivatives, such as N-n-butyl-N-vinylformamides and N-iso-butyl-N-vinylformamides were synthesized and copolymerized with N-vinylformamide and N-methyl-N-vinylacetamide. Lower critical solution temperature values of the copolymers were observed at a wide range of temperatures. Thermosensitive behaviors of copolymers were controlled not only by the induction rate of alkylation of N-vinylamides at the amide position but also by the chemical structures, including hydrogen atom of secondary amide group.
掲載誌名
Chemistry Letters
ISSN
13480715
出版者
Oxford University Press|Chemical Society of Japan
45
6
開始ページ
589
終了ページ
591
発行日
2016-03-03
権利情報
This is a pre-copyedited, author-produced version of an article accepted for publication in Chemistry Letters following peer review. The version of record Ryo Kawatani, Kai Kan, Malcolm A Kelland, Mitsuru Akashi, Hiroharu Ajiro, Remarkable Effect on Thermosensitive Behavior Regarding Alkylation at the Amide Position of Poly(N-vinylamide)s, Chemistry Letters, Volume 45, Issue 6, June 2016, Pages 589–591, is available online at: https://doi.org/10.1246/cl.160145
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言語
eng
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