Total for the last 12 months
number of access : ?
number of downloads : ?
ID 115342
Title Alternative
STEREOSPECIFIC RADICAL POLYMERIZATION
Author
Nasu, Shou Tokushima University
Morikami, Akihiro Tokushima University
Keywords
radical polymerization
stereospecific polymerization
isotactic
syndiotactic
N-methyl-N-phenylacrylamide
monomer conformation
Content Type
Journal Article
Description
Radical polymerization of N-methylacrylamide (NMAAm), N,N-dimethylacrylamide (DMAAm), and N-methyl-N-phenylacrylamide (MPhAAm) was investigated in toluene at low temperatures. Atactic, isotactic, and syndiotactic polymers were obtained by the polymerization of NMAAm, DMAAm, and MPhAAm, respectively, indicating that the stereospecificity of the radical polymerization of acrylamide derivatives depended on the N-substituents of the monomer used. From the viewpoint of monomer structure, the origin of the stereospecificity of radical polymerization of NMAAm derivatives is discussed.
Journal Title
Journal of Polymer Science Part A : Polymer Chemistry
ISSN
0887624X
10990518
NCID
AA1068915X
AA11624127
Publisher
Wiley
Volume
47
Issue
23
Start Page
6534
End Page
6539
Published Date
2009-10-27
Rights
This is the peer reviewed version of the following article: Hirano, T., Nasu, S., Morikami, A. and Ute, K. (2009), The effect of the N‐substituent s‐trans to the carbonyl group of N‐methylacrylamide derivatives on the stereospecificity of radical polymerizations. J. Polym. Sci. A Polym. Chem., 47: 6534-6539., which has been published in final form at https://doi.org/10.1002/pola.23696. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
EDB ID
DOI (Published Version)
URL ( Publisher's Version )
FullText File
language
eng
TextVersion
Author
departments
Science and Technology