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ID 113019
著者
小笠原, 正道 Tokushima University|Hokkaido University 徳島大学 教育研究者総覧
Tseng, Ya-Yi Osaka Prefecture University
Liu, Qiang Tokushima University|Hokkaido University
Chang, Ninghui Hokkaido University
Yang, Xicheng Hokkaido University
Takahashi, Tamotsu Hokkaido University
Kamikawa, Ken Osaka Prefecture University
資料タイプ
学術雑誌論文
抄録
Kinetic resolution of racemic planar-chiral (η5-1-alkenyl-2-bromocyclopentadienyl)manganese(I) complexes 1 was realized by the molybdenum-catalyzed asymmetric ring-closing metathesis. While vinyl-Cp derivative 1a was resolved in excellent enantioselectivity with the krel values of up to 127, the selectivity in the ARCM reaction of allyl-Cp derivative 1b was modest (krel = 3.0). ARCM product 2a, which was obtained in an enantiomerically pure form by the two successive ARCM reactions or recrystallization of the enantiomerically enriched products, was found to be a versatile synthetic precursor to various planar-chiral cymantrene derivatives.
掲載誌名
Organometallics
ISSN
02767333
15206041
cat書誌ID
AA10627775
AA12097286
出版者
ACS Publications
36
7
開始ページ
1430
終了ページ
1435
発行日
2017-03-23
権利情報
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organometallics, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.organomet.7b00125.
EDB ID
出版社版DOI
出版社版URL
フルテキストファイル
言語
eng
著者版フラグ
著者版
部局
理工学系