ID 113058
著者
Higashino, Tomohiro Kyoto University
Yamada, Tomoki Kyoto University
Yamamoto, Masanori Kyoto University
古部, 昭広 National Institute of Advanced Industrial Science and Technology (AIST)|Tokushima University 徳島大学 教育研究者総覧 KAKEN研究者をさがす
Tkachenko, Nikolai V. Tampere University of Technology
Miura, Taku Kobe University
Kobori, Yasuhiro Kobe University|(Japan) Science and Technology Agency
Jono, Ryota The University of Tokyo
Yamashita, Koichi The University of Tokyo
Imahori, Hiroshi Kyoto University
キーワード
charge separation
electron transfer
electronic coupling
exciplexes
Marcus theory
資料タイプ
学術雑誌論文
抄録
The unprecedented dependence of final charge separation efficiency as a function of donor–acceptor interaction in covalently-linked molecules with a rectilinear rigid oligo-p-xylene bridge has been observed. Optimization of the donor–acceptor electronic coupling remarkably inhibits the undesirable rapid decay of the singlet charge-separated state to the ground state, yielding the final long-lived, triplet charge-separated state with circa 100% efficiency. This finding is extremely useful for the rational design of artificial photosynthesis and organic photovoltaic cells toward efficient solar energy conversion.
掲載誌名
Angewandte Chemie International Edition
ISSN
14337851
15213773
cat書誌ID
AA0052535X
AA11614189
出版者
Wiley-VCH Verlag GmbH & Co. KGaA
55
2
開始ページ
629
終了ページ
633
発行日
2015-11-26
権利情報
© 2015 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution Non-Commercial NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made.
EDB ID
308210
出版社版DOI
出版社版URL
フルテキストファイル
言語
eng
著者版フラグ
出版社版
部局
理工学系