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ID 114284
著者
Sato, Fumiaki Tokushima University
Ariki, Kenta Tokushima University
キーワード
Flavin
Polymer-supported catalyst
Hydrogenation
Photooxidation
資料タイプ
学術雑誌論文
抄録
Riboflavin tetramethacrylate (RFlTMA) was prepared as a flavin monomer and copolymerized with ethylene glycol dimethacrylate (EGDMA) under polymerization-induced phase separation conditions. The resulting flavin-containing mesoporous network polymer, poly(RFlTMA-co-EGDMA), was found to be a more effective catalyst than riboflavin tetraacetate (RFlTA), a soluble analogue, for aerobic hydrogenation of olefins despite its heterogeneity, which allowed for its multiple recovery and reuse through simple filtrations and washings without loss in catalytic activity. In addition, the polymeric flavin was demonstrated to be utilized also as an effective photocatalyst in the oxidation of benzyl alcohols.
掲載誌名
Tetrahedron Letters
ISSN
00404039
cat書誌ID
AA00861801
AA11539822
出版者
Elsevier
61
14
開始ページ
151710
発行日
2020-02-04
備考
論文本文は2022-02-04以降公開予定
権利情報
© 2020. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
EDB ID
出版社版DOI
出版社版URL
言語
eng
著者版フラグ
その他
部局
理工学系
教養教育院