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ID 115353
著者
Kamikubo, Takahiro Tokushima University
Okumura, Yuya Tokushima University
キーワード
N-Isopropylacrylamide
Heterotactic polymer
Radical polymerization
資料タイプ
学術雑誌論文
抄録
Radical polymerization of N-isopropylacrylamide in toluene at –40°C in the presence of fourfold amounts of fluorinated alcohols was investigated. The 13C NMR analysis of the obtained polymers suggested that the addition of fluorinated alcohols induced heterotactic-specificity in radical polymerization of NIPAAm, although syndiotactic poly(NIPAAm)s were obtained by adding alkyl alcohols as we have previously reported. To the best of our knowledge, this is the first synthesis of heterotactic poly(NIPAAm).
掲載誌名
Polymer
ISSN
00323861
cat書誌ID
AA11537383
出版者
Elsevier
48
17
開始ページ
4921
終了ページ
4925
発行日
2007-07-04
権利情報
© 2007. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
EDB ID
出版社版DOI
出版社版URL
フルテキストファイル
言語
eng
著者版フラグ
著者版
部局
理工学系