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ID 117329
著者
Kimura, Yuki Tokushima University
Ohashi, Eisaku Tokushima University
Taniguchi, Takashi Tokushima University
Imagawa, Hiroshi Tokushima Bunri University
資料タイプ
学術雑誌論文
抄録
The first total syntheses of two 4,10-dihydroxy 8,12-guaianolides that were reported to be natural products, were achieved. Toward the syntheses of a collection of related guaianolides, the typical 5,7-fused system of 8,12-guaianolides was constructed by a ring expansion reaction of a hydroxylated coronafacic acid analog that can be practically synthesized and optically resolved. The total syntheses of these compounds revealed that the previously reported structures of both natural products were incorrect.
掲載誌名
Organic Letters
ISSN
15237060
15237052
cat書誌ID
AA11347843
AA1218968X
出版者
ACS Publications
24
17
開始ページ
3297
終了ページ
3301
発行日
2022-04-21
権利情報
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.2c01215.
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出版社版DOI
出版社版URL
フルテキストファイル
言語
eng
著者版フラグ
著者版
部局
薬学系