ID 109943
著者
杉山, 茂 Department of Advanced Materials, Institute of Technology and Science, The University of Tokushima|Department of Resource Circulation Engineering, Center for Frontier Research of Engineering, The University of Tokushima 徳島大学 教育研究者総覧 KAKEN研究者をさがす
オカダ, ヤスヒロ Department of Chemical Science and Technology, The University of Tokushima
コサカ, ヨウヘイ Department of Chemical Science and Technology, The University of Tokushima
中川, 敬三 Department of Advanced Materials, Institute of Technology and Science, The University of Tokushima|Department of Resource Circulation Engineering, Center for Frontier Research of Engineering, The University of Tokushima KAKEN研究者をさがす
加藤, 雅裕 Department of Advanced Materials, Institute of Technology and Science, The University of Tokushima 徳島大学 教育研究者総覧 KAKEN研究者をさがす
カトウ, ユウキ Otake Research Laboratories, Mitsubishi Rayon Co. Ltd.
アキハラ, シュウジ Otake Research Laboratories, Mitsubishi Rayon Co. Ltd.
ヤスカワ, トシヤ Otake Research Laboratories, Mitsubishi Rayon Co. Ltd.
ニノミヤ, ワタル Otake Research Laboratories, Mitsubishi Rayon Co. Ltd.
キーワード
Catalytic Conversion
1,2-Propandiol
Propanal
FSM-16
資料タイプ
学術雑誌論文
抄録
The catalytic conversion of 1,2-propandiol to propanal is examined using FSM-16 particles (0.85-1.70 mm) molded by wet-treatment and pressurization. When FSM-16 was molded with 0.6 g of pressurization and supplied to the catalytic conversion of 1,2-propandiol at 673 K, this system resulted in a 94.8% conversion of 1,2-propandiol and 90.5% selectivity to propanal at 0.25 h on-stream, which was the maximum amount of activity. However, at 4.50 h on-stream, the activity decreased extremely to deactivation 19.9% conversion of 1,2-propandiol and 84.7% selectivity to propanal. In contrast, when FSM-16 molded with wet-treatment (0.15 g) was used for the conversion at 573 K, activity was greatly increased and stable 98.6% conversion of 1,2-propandiol and 56.2% selectivity to propanal at 0.25 h on-stream followed by 91.9% and 52.5%, respectively, at 4.50 h on-stream. The hexagonal structure of FSM-16 was suggested to have contributed to the suitable conversion of 1,2-propandiol to propanal.
掲載誌名
Journal of Chemical Engineering of Japan
ISSN
00219592
cat書誌ID
AA00709658
46
9
開始ページ
620
終了ページ
624
並び順
620
発行日
2013
備考
Copyright © 2013 The Society of Chemical Engineers, Japan
EDB ID
出典
Journal of Chemical Engineering of Japan (2013) Vol.46 No.9, p.620–624 (DOI: 10.1252/jcej.13we059)
出版社版URL
フルテキストファイル
言語
eng
著者版フラグ
著者版
部局
理工学系