| ID | 114094 |
| タイトル別表記 | Synthesis of Allenyl Esters by Horner-Wadsworth-Emmons Reactions of Ketenes Mediated by i-PrMgBr
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| 著者 |
Matsumoto, Tomoya
Tokushima University
Yano, Teppei
Tokushima University
Toguchi, Munehisa
Tokushima University
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| キーワード | Horner-Wadsworth-Emmons reaction
allene
ketene
Grignard reagent
fluorine
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| 資料タイプ |
学術雑誌論文
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| 抄録 | The synthesis of conjugated allenyl esters (trisubstituted allenes) was achieved by the Mg(II)-mediated Horner-Wadsworth-Emmons reaction of methyl bis(2,2,2-trifluoroethyl)phosphonoacetate with di-substituted ketenes. In addition, a novel access to α-fluorinated allenyl carboxamides (tetra-substituted allenes) is presented.
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| 掲載誌名 |
Synlett
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| ISSN | 09365214
14372096
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| cat書誌ID | AA10731110
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| 出版者 | Georg Thieme Verlag
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| 巻 | 26
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| 号 | 15
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| 開始ページ | 2135
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| 終了ページ | 2138
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| 発行日 | 2015-08-10
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| EDB ID | |
| 出版社版DOI | |
| 出版社版URL | |
| フルテキストファイル | |
| 言語 |
eng
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| 著者版フラグ |
著者版
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| 部局 |
薬学系
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