ID | 115121 |
著者 |
Toguchi, Munehisa
Tokushima University
Shimabukuro, Yuki
Tokushima University
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キーワード | Thia-Michael/Dieckmann condensation
Trisubstituted thiophene
Allenyl ester
Methyl mercaptoacetate
Magnesium bromide
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資料タイプ |
学術雑誌論文
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抄録 | Tandem thia-Michael/Dieckmann condensation of allenyl esters with methyl mercaptoacetate in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene afforded 2,3,5-trisubstituted thiophenes regioselectively. On the other hand, 2,3,4-trisubstituted thiophenes were obtained as the sole product by tandem thia-Michael/Dieckmann condensation employing magnesium bromide and triethylamine.
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掲載誌名 |
Tetrahedron Letters
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ISSN | 00404039
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cat書誌ID | AA00861801
AA11539822
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出版者 | Elsevier
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巻 | 61
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号 | 36
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開始ページ | 152271
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発行日 | 2020-07-27
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権利情報 | © 2020. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
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EDB ID | |
出版社版DOI | |
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フルテキストファイル | |
言語 |
eng
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著者版フラグ |
著者版
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部局 |
薬学系
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