| ID | 119050 |
| 著者 |
Mori, Daiki
Tokushima University
|
| キーワード | Guanidine
Carbodiimide
Polyaddition
Polymeric catalyst
Asymmetric reaction
|
| 資料タイプ |
学術雑誌論文
|
| 抄録 | A novel biscarbodiimide compound containing alkynyl spacer has been prepared and successfully used as an electrophilic comonomer in the polyaddition reaction with chiral secondary and primary 1,2-diamines. The resulting chiral polyguanidines have exhibited Brønsted base catalytic activities with asymmetric induction ability, which can be greatly enhanced through noncovalent modification with achiral Brønsted acids, such as phosphoric acid diesters and carboxylic acids. This study reveals for the first time the validity of a strategy incorporating guanidine functionality into polymer main chains followed by their noncovalent modification for organocatalyst design.
|
| 掲載誌名 |
Molecular Catalysis
|
| ISSN | 24688274
24688231
|
| 出版者 | Elsevier
|
| 巻 | 557
|
| 開始ページ | 113973
|
| 発行日 | 2024-02-28
|
| 備考 | 論文本文は2026-02-28以降公開予定
|
| 権利情報 | © 2024. This manuscript version is made available under the CC-BY-NC-ND 4.0 license https://creativecommons.org/licenses/by-nc-nd/4.0/
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| EDB ID | |
| 出版社版DOI | |
| 出版社版URL | |
| 言語 |
eng
|
| 著者版フラグ |
その他
|
| 部局 |
教養教育院
理工学系
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