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ID 111874
著者
Hayashi, Tsukiho Tokushima University
Osawa, Ayumi Hokkaido University
Watanabe, Takehiro Suntory Foundation of Life Sciences
Murata, Yoshiko Suntory Foundation of Life Sciences
キーワード
iron ion sensor
fluorescence quenching
1,3a,6a-triazapentalene
enterobactin
siderophore
資料タイプ
学術雑誌論文
抄録
1,3a,6a-Triazapentalene (TAP)-labeled enterobactin was developed as an iron ion sensor. 3-Acetylated-TAP was successfully introduced to the catechol ring of enterobactin, a well-recognized siderophore secreted by various Gram-negative bacteria. The fluorescence of TAPlabeled enterobactin decreased gradually as the amount of Fe3+ ion as an additive was increased, and 1.2 equiv of Fe3+ ion completely quenched the fluorescence. In clear contrast, when other metal ions were used, the fluorescence of TAP-labeled enterobactin remained even at 5.0 equiv.
掲載誌名
Tetrahedron Letters
ISSN
00404039
cat書誌ID
AA00861801
AA11539822
出版者
Elsevier
58
20
開始ページ
1961
終了ページ
1964
発行日
2017-04-05
権利情報
© 2017. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
EDB ID
出版社版DOI
出版社版URL
フルテキストファイル
言語
eng
著者版フラグ
著者版
部局
薬学系