| ID | 113017 |
| 著者 |
Sasa, Hirotaka
Ritsumeikan University
Hu, Hao
Tokushima University|Hokkaido University
Amano, Yuta
Ritsumeikan University
Nakajima, Hikaru
Hokkaido University
Takenaga, Naoko
Meijo University
Nakajima, Kiyohiko
Aichi Universiy of Education
Kita, Yasuyuki
Ritsumeikan University
Takahashi, Tamotsu
Hokkaido University
Dohi, Toshifumi
Ritsumeikan University
|
| 資料タイプ |
学術雑誌論文
|
| 抄録 | The C2-symmetric tetralin-fused 1,4-diiodo-1,3-butadiene derivatives, (Z,Z)-2,3-di(1-iodoalkylidene)tetralin 1a-c, are atropisomeric and can be resolved into the two persistent axially chiral enantiomers by HPLC on a chiral stationary phase. The enantiomerically pure compounds can serve as chiral organocatalysts for dearomatizing spirolactonization to show good performances in up to 73 % ee.
|
| 掲載誌名 |
Organic Letters
|
| ISSN | 15237060
15237052
|
| cat書誌ID | AA11347843
AA1218968X
|
| 出版者 | ACS Publications
|
| 巻 | 19
|
| 号 | 15
|
| 開始ページ | 4102
|
| 終了ページ | 4105
|
| 発行日 | 2017-07-20
|
| 権利情報 | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.7b01876.
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| EDB ID | |
| 出版社版DOI | |
| 出版社版URL | |
| フルテキストファイル | |
| 言語 |
eng
|
| 著者版フラグ |
著者版
|
| 部局 |
理工学系
|
