ID | 115148 |
著者 |
Moriuchi, Toshiyuki
Osaka City University
Moriuchi-Kawakami, Takayo
Osaka Institute of Technology
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キーワード | chirality induction
helical chirality
bioorganometallic conjugate
dipeptide
nucleobase
ferrocene
organogold(I)
self-assembly
hydrogen bond
Au(I)–Au(I) interaction
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資料タイプ |
学術雑誌論文
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抄録 | Considerable attention has been given to the research field of bioorganometallic chemistry, which is a hybrid chemistry field between biology and organometallic chemistry. The introduction of biomolecules, which have hydrogen bonding sites and chiral centers, into organometallic compounds is a promising strategy to construct chirality-organized bioorganometallic conjugates. This feature paper sketches an outline of induction of helical chirality into bioorganometallic conjugates by the control of a torsional twist of the organometallic moiety. Topics covered included control of the helical chirality of 1,n′-disubstituted ferrocene moieties in ferrocene-dipeptide conjugates, and the chirality induction of the Au(I)–Au(I) axis in the dinuclear organogold(I)-uracil conjugates.
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掲載誌名 |
Inorganics
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ISSN | 23046740
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出版者 | MDPI
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巻 | 6
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号 | 4
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開始ページ | 111
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発行日 | 2018-10-13
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権利情報 | © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
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言語 |
eng
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出版社版
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部局 |
理工学系
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