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ID 117574
著者
Takechi, Nao Tokushima University
Yamanomoto, Ken Tokushima University
キーワード
Flavin
Peptide
Aerobic oxidation
DFT calculation
資料タイプ
学術雑誌論文
抄録
The original flavopeptide catalyst, 3-FlC2-L-Pro-L-Tyr-L-Asp-Ado-NH-PS (Fl-PepLLL), and its diastereomers including Fl-PepDDL, Fl-PepLDL, and Fl-PepDLL were synthesized to investigate the correlation between their catalytic activity and stereochemistry. The results and related computations showed the importance of intramolecular hydrogen bonds involving the Asp residue in their 4a-hydroperoxy forms for the catalysis.
掲載誌名
Tetrahedron Letters
ISSN
00404039
cat書誌ID
AA00861801
AA11539822
出版者
Elsevier
73
開始ページ
153107
発行日
2021-04-22
権利情報
© 2021. This manuscript version is made available under the CC-BY-NC-ND 4.0 license https://creativecommons.org/licenses/by-nc-nd/4.0/
EDB ID
出版社版DOI
出版社版URL
フルテキストファイル
言語
eng
著者版フラグ
著者版
部局
理工学系
教養教育院